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/ Members /

Faculty
Contract-employed Professor
Adjunct Professor
Emeritus Chair Professor
Retired Professor
Staff

Liang-Shiu Lee

/ Education /

Ph.D. in Chemistry, Clemson University, USA (1984)
B.S. in Chemistry, National Tsing Hua University (1977)

/ Experience /

Professor, Department of Chemistry, National Sun Yat-sen University (1994)
Associate Professor, Department of Chemistry, National Sun Yat-sen University (1984)
The primary focus of our research group is studying the reactions and kinetics of metal coordination compounds in their excited states.

Our methods include selecting and synthesizing ligands, synthesizing and characterizing metal coordination compounds (through spectroscopic and magnetic measurements), investigating photochemical reaction mechanisms, measuring quantum yields, and using ligand field theory models to explain experimental results.

We aim to understand the interactions between metals and ligands in metal coordination compounds by corroborating theoretical calculations with experimental results. Specifically, we investigate how ligands affect the chemical properties of these compounds in their excited states. The ultimate goal is to design practical photocatalytic systems. We have achieved significant results in the photocatalytic reactions of cage-like trivalent cobalt compounds.

/ Works /

1. Huang, M. F.; Lee, L. “The Temperate Dependence Study of Oscillation Period of BR Reaction” Chemistry (The Chinese Chem. Soc., Taiwan, China) 1993, 51, 71.

2. Lee, L.; Yuan, C. H. “Photosensitization Study of Cage-like Metal Complexes with Hexadentate Ligands, tptn and tpen. Part 1. Photochemistry and Spectroelectrochemistry of Iron(ll), Cobalt(lll) and Nickel(ll) Complexes” J. Photochem.Photobio. A: Chem. 1993, 70, 253.

3. Lee, L.; Yuan, C. H. “Photosensitization Study of Cage-like Metal Complexe with Hexadentate Ligands, tptn and tpen. Part 2. Electron Transfer Photosensitization via lon Pairs: Cobalt(lll)(tptn)-iodide lon and Cobalt(lll)(tpen)-iodide lon Systems” J. Photochem. Photobio. A: Chem. 1993, 70, 261.

4. Hwang, W. S.; Lee. L.; Yu. W. R. “Electrooxdation of Tricarbonyl( N ,N-diphenylcyclohexadienecarboxamide)iron Complexes. Reversibility of Electron Transfer and Free Energy Change” J. Chin. Chem. Soc. 1993, 40, 263.

5. Lee, L. ”Angular Overlap Model Approach to Explain the Trans-Effect in d8 Square Planar Metal Complexes” J. Chem. Edu. 1994, 71, 644.

6. Lee. L.; Wang, C. H. “Photoaquation and Aquation of Trans- Dichlorobis(bipyridine)rethenium(III)” J. Photochem.Photobio. A: Chem. 1994, 79, 163.

7. Lin, J. T.; Sun, S. -S.; Wu, J. J.; Lee, L.; Lin, K. -J.; Huang, Y. F. “Dinuclear Metal Carbonyls Bridged by Pyridyl Ligands Incorporating an Alkyne Entity” Inorg. Chem. 1995, 34, 2323.

8. 1. D. L. Wang, W. S. Hwang, L. C. Liang, Lein. I. Wang, L. Lee, M. Y. Chiang, “Reaction of Thienyl Schiff Base with Diiron Nonacarbonyl” Organometallics 1997, 16, 3109.

9. D. L. Wang, W. S. Hwang, L. Lee, M. Y. Chiang; “Reaction of N-(3-methyl-2-thienylmethylidene) aniline with Diiron Nonacarbonyl: Cyclometalation induced methyl migration, imidoyl complex formation, and hydrogenation” J. Organometallic Chem. 1997, 579, 211.

10. W. S. Hwang, C. J. Hwang, D. L. Wang, L. Lee, M. Y. Chiang; “Synthesis and Structure of 1-(2-Thienylmethyl)-2-(2-thienyl)bezimidazole and its Cu(I) and Ag(I) Complexes” J. Chin. Chem. Soc. 1998, 45, 555.

11. T. Y. Dong, L. Lee, C. H. Cheng, L. S. Chang, M. Y. Chiang; “Complexation behavior of 1,1”:1’,1”’-bis(1,4 ,10 13-tetraoxa-7,16-diazacyclooctadecane-7,16-diyldimethyl)bisferrocene” J. Organomettallic Chem. 2001, 625, 173.

12. L. Lee; “Introduction to Inorganic Photochemistry”, Chemistry (The Chinese Chem. Soc. Taipei), 2002, 60(4), 653.

13. C. H. Cheng, F. D. Yen, L. Lee; “Photochemical Reactions of Methanol or Isopropanol and Cage-like Co(III) Complexes” Chemistry (The Chinese Chem. Soc. Taipei), 2003.

14. T. Y. Dong, M. C. Lin, L. Lee, C. H. Cheng, S. H. Peng, G. H. Lee; “Pronounced Effects of Grinding on Rates of Intramolecular Electron Transfer in Mixed-Valence 1’,2’,1’’’,2’’’-Tetranaphthylmethyl- and 1’,3’,1’’’,3’’’- Tetranaphthylmethyl-Biferrocenium Triiodides” J. Organomettallic Chem. 2003, 679, 181-193.

15. T. Y. Dong, Kellen Chen, M. C. Lin, and L. Lee; Toward the Development of Molecular Wires: Ruthenium(II) Terpyridine Complexes Containing Polyferrocenyl as a Spacer; Organometallics ,24, 4198-4206(2005).—-(SCI)

16. S. F. Ko, C. C. Huang, M. J. Hsieh, S. H. Ng, C. C. Lee, C. C. Lee, T. K. Lin, M. C. Chen, M. C. Chen, L. Lee, 31P MR Spectroscopic Assessment of Muscle in Patients with Myasthenia Gravis befor and after Thymectomy: Initial Experience, Radiology 2008, 247(1), 162.

17. L. Lee, “A Simplified Approach to the Basis Functions of Symmetry Operations and Terms of Metal Complexes in an Octahedral Field with d1 to d9 Configurations”, J. Chem. educ. 87(2), 2010, 172.

1. 李良修，走過帕金森幽谷，天下文化，台北，1999。

2. 李良修，我懂了！量子力學，商周出版社，台北，2004。

/ Patents /