梁蘭昌 教授  

◆研究室:C5002

◆實驗室:C5004

◆電話:(075252000 3945

e-maillcliang@mail.nsysu.edu.tw

http://chem.nsysu.edu.tw/ezfiles/84/1084/img/780/lc_liang.jpg 

 


學經歷

◇美國 史丹佛大學 博士後研究 (1999-2000)
◇美國 麻省理工學院 博士 (1999)


研究興趣

  有機金屬化學、配位化學、有機化學、勻相催化、高分子材料化學

The research projects in my group mainly involve exploratory synthetic, structural, and reactivity studies on novel organometallic and inorganic systems with an ultimate goal of developing practical catalysts for specific chemical transformations. Design and synthesis of metal complexes as well as reactivity exploration play an integral role of the research. Synthesis and manipulation of new compounds rely primarily on standard inert-atmosphere glove box or vacuum-line techniques. A variety of spectroscopic instruments is used to optimize synthetic conditions, to measure reaction kinetics, and to characterize new compounds. Current research topics include:
  Ring-opening polymerization catalysis

http://chem.nsysu.edu.tw/ezfiles/84/1084/img/780/lc_liang-1.png

  Cross-coupling catalysis

http://chem.nsysu.edu.tw/ezfiles/84/1084/img/780/lc_liang-2.png

  Metal-ligand multiple bonds

http://chem.nsysu.edu.tw/ezfiles/84/1084/img/780/lc_liang-3.png

  Small molecule activation

http://chem.nsysu.edu.tw/ezfiles/84/1084/img/780/lc_liang-4.png


代表著作

1.      Amido Pincer Complexes of Nickel(II): Synthesis, Structure, and Reactivity
Liang, L.-C.; Chien, P.-S.; Lin, J.-M.; Huang, M.-H.; Huang, Y.-L.; Liao, J.-H.
Organometallics 2006, 25, 1399-1411.

2.      Metal Complexes of Chelating Diarylamido Phosphine Ligands
Liang, L.-C.
Coord. Chem. Rev. 2006, 250, 1152-1177.
An invited contribution to “Recent developments in organometallic chemistry: 2006”.

3.      Intermolecular Arene C-H Activation by Nickel(II)
Liang, L.-C.; Chien, P.-S.; Huang, Y.-L.
J. Am. Chem. Soc. 2006, 128, 15562-15563.

4.      Preparation and Structural Characterization of Group 1 Metal Complexes Containing a Chelating Biphenolato Phosphine Ligand
Chang, Y.-N.; Liang, L.-C.
Inorg. Chim. Acta 2007, 360, 136-142.
An invited contribution to the Special Issue “Inorganic Chemistry – The Next Generation”.

5.      Biphenolate Phosphine Complexes of Group 4 Metals
Liang, L.-C.; Chang, Y.-N.; Lee, H. M.
Inorg. Chem. 2007, 46, 2666-2673.

6.      Biphenolate Phosphine Complexes of Tin(IV)
Liang, L.-C.; Chang, Y.-N.; Chen, H.-S.; Lee, H. M.
Inorg. Chem. 2007, 46, 7587-7593.

7.      Nickel(II) Complexes Containing Bidentate Amido Phosphine Ligands Derived from α-Iminophosphorus Ylides: Synthesis and Structural Characterization
Lee, P.-Y.; Liang, L.-C.
Inorg. Chem. 2008, 47, 749-758.

8.      Fluorinated Diarylamido Complexes of Lithium, Zirconium, and Hafnium
Lee, W.-Y.; Liang, L.-C.
Inorg. Chem. 2008, 47, 3298-3306.

9.      Terminal Nickel(II) Amide, Alkoxide, and Thiolate Complexes Containing Amido Diphosphine Ligands of the Type [N(o-C6H4PR2)2]− (R = Ph,iPr, Cy)
Liang, L.-C.; Chien, P.-S.; Lee, P.-Y. ; Lin, J.-M.; Huang, Y.-L.
Dalton Trans. 2008, 3320-3327.

10.  Phosphorus and Olefin Substituent Effects on the Insertion Chemistry of Nickel(II) Hydride Complexes Containing Amido Diphosphine Ligands
Liang, L.-C. ; Chien, P.-S.; Lee, P.-Y.
Organometallics 2008, 27, 3082-3093.

11.  Synthesis and Structural Characterization of Five-coordinate Aluminum Complexes Containing Diarylamido Diphosphine Ligands
Lee, P.-Y.; Liang, L.-C.
Inorg. Chem. 2009, 48, 5480–5487.

12.  Biphenolate Phosphine Complexes of Tantalum
Liang, L.-C.; Cheng, L.-C.; Tsai, T.-L.; Hu, C.-H.; Guo, W.-H.
Inorg. Chem. 2009, 48, 5697–5703.

13.  Amido Phosphine Complexes of Zinc: Synthesis, Structure, and Catalytic Ring-opening Polymerization of ε-Caprolactone
Liang, L.-C.; Lee, W.-Y.; Tsai, T.-L.; Hsu, Y.-L.; Lee, T.-Y.
Dalton Trans. 2010, 39, 8748-8758.

14.  Aluminum Complexes of Bidentate N,O- and N,N-Ligands Derived from Oxidative Functionalization of Amido Phosphines: Synthesis, Structure, and Reactivity
Liang, L.-C.; Chen, F.-Y.; Huang, M.-H.; Cheng, L.-C.; Li, C.-W.; Lee, H. M.
Dalton Trans. 2010, 39, 9941-9951.

15.  Alkali Metal Complexes of a tert-Butylphosphine-bridged Biphenolate Ligand
Hsu, Y.-L.; Liang, L.-C.
Organometallics 2010, 29, 6201-6208.

16.  Group 4 Complexes of a tert-Butylphosphine-bridged Biphenolate Ligand
Liang, L.-C.; Hsu, Y.-L.; Lin, S.-T.
Inorg. Chem. 2011, 50, 3363-3372.

17.  Synthesis, Structure, and Ring-opening Polymerization Catalysis of Zinc Complexes Containing Amido Phosphinimine Ligands
Liang, L.-C.; Tsai, T.-L.; Li, C.-W.; Hsu, Y.-L.; Lee, T.-Y.
Eur. J. Inorg. Chem. 2011, 2948-2957.

18.  A Terminal Nickel(II) Anilide Complex Featuring an Unsymmetrically Substituted Amido Pincer Ligand: Synthesis and Reactivity
Liang, L.-C.; Li, C.-W.; Lee, P.-Y.; Chang, C.-H.; Lee, H. M.
Dalton Trans. 2011, 40, 9004-9011.
An invited contribution to the themed issue entitled “Pincers and other hemilabile ligands”.

19.  Synthesis and Structural Characterization of Lithium and Iron Complexes Containing a Chelating Phenolate Phosphine Ligand
Liang, L.-C.; Chang, Y.-N.; Shih, H.-Y.; Lin, S.-T.; Lee, H. M.
Eur. J. Inorg. Chem. 2011, 4077-4082.
An invited contribution to a special issue on “Polar Intermetallics, Clusters and Cluster Complexes”. Dedicated to Professor John Corbett on the occasion of his 85th birthday.

20.  Zirconium Complexes Containing a Diarylamido Diphosphine Ligand: Structural Preferences Controlled by Ligand Electronics and Sterics
Liang, L.-C.; Chien, P.-S.; Hsiao, Y.-C.; Li, C.-W.; Chang, C.-H.
J. Organomet. Chem. 2011, 696, 3961-3965.
An invited contribution to a special issue on “Small Molecule Activation and Catalysis Invoking Metal-Carbon Multiple Bonds”. Dedicated to Professor Kenneth G. Caulton on the occasion of his 70th birthday.

21.  Nickel Complexes Incorporating an Amido Phosphine Chelate with a Pendant Amine Arm: Synthesis, Structure, and Catalytic Kumada Coupling
Liang, L.-C.; Lee, W.-Y.; Hung, Y.-T.; Hsiao, Y.-C.; Cheng, L.-C.; Chen, W.-C.
Dalton Trans. 2012, 41, 1381-1388.

22.  Synthesis and Structural Characterization of Zinc Complexes Containing Chelating Phenolate Phosphine Ligands
Liang, L.-C.; Shih, H.-Y.; Chen, H.-S.; Lin, S.-T.
Eur. J. Inorg. Chem. 2012, 298-305.

23.  Divergent Carbonylation Reactivity Preferences of Nickel Complexes Containing Amido Pincer Ligands: Migratory Insertion versus Reductive Elimination
Liang, L.-C.; Hung, Y.-T.; Huang, Y.-L.; Chien, P.-S.; Lee, P.-Y.; Chen, W.-C.
Organometallics 2012, 31, 700-708.

24.  Lithium Complexes of Tridentate Amine Biphenolate Ligands Containing Distinct N-alkyl Substituents
Liang, L.-C.; Lin, S.-T.; Chien, C.-C.
Polyhedron2013, 52, 1090–1095.
An invited contribution to a special issue on “the 100th anniversary of the award of the
Nobel Prize in Chemistry to Professor Alfred Werner”.

25.  Titanium Complexes of Tridentate Aminebiphenolate Ligands Containing Distinct N-Alkyls: Profound N-Substituent Effect on Ring-Opening Polymerization Catalysis
Liang, L.-C.; Lin, S.-T.; Chien, C.-C.
Inorg. Chem. 2013, 52, 1780–1786.

26.  Zirconium and Hafnium Complexes Containing N-alkyl Substituted Amine Biphenolate Ligands: Coordination Chemistry and Living Ring-opening Polymerization Catalysis
Liang, L.-C.; Lin, S.-T.; Chien, C.-C.; Chen, M.-T.
Dalton Trans. 2013,42, 9286-9293.
A contribution to a themed issue on “Advances in metal-catalyzed polymerization and related transformations”.

27.  Zirconium and Hafnium Complexes Containing N-alkyl Substituted Amine Biphenolate Ligands: Unexpected Ligand Degradation and Divergent Complex Constitutions Governed by N-alkyls
Liang, L.-C.; Chien, C.-C.; Chen, M.-T.; Lin, S.-T.
Inorg. Chem. 2013,52, 7709–7716.