周金興教授

研究室:4025  實驗室:4030

電話: (07)5252000 ext 3915

e-mail:ch-chou@mail.nsysu.edu.tw

 

實驗室相簿


兼系主任(2000.8-2003.7)

教授(1995)

副教授(1987)

美國哈佛大學博士後研究 (1987)

美國愛敏斯實驗室博士後研究(1985)

美國愛荷華州立大學博士(1985)

成功大學理學士(1972)


研究興趣
本研究室之研究重點在於利用瞬間真空熱解法來合成以一般的合成方法不易得到的不穩定化合物,進而研究此類化合物的化性,物性及其應用。

我們正在研究的不穩定化合物包括:〔I〕二亞甲基苯類化合物〔1及2〕;〔II〕氧及硫化丙二烯〔3及4〕〔III〕碳烯及氮烯類化合物〔5及6〕。除了瞬間真空熱解法,我們也利用低溫核磁共振技術及流體核磁共振技術來偵測此類化合物及做動力學方面的研究。


代表著作

1.     Huang, C. S.; Peng, C. C.; Chou, C. H.* 1994, "Reaction of    2,5-Dimethylene-2,5- dihydrothiophene with Triplet Oxygen" Tetrahedron Lett. 35, 4175-4176.

2.     Tseng, P. W.; Chou, C. H.* 1994, "Synthesis of 1-Methyl-2,5-dimethylene-
2,5-dihydropyrrole by the Flash Vacuum Pyrolysis of N-(1,5-Dimethyl-2-Pyrryl)methyl Benzamide" J. Chin. Chem. Soc. 41, 579-583.

3.     Chen, P. S.; Chou, C. H.* 1994, "Pyrolytic Chemistry of Benzyl Benzoate" J. Chin. Chem. Soc. 41, 597-599.

4.     Chou, C. H.*; Wu, C. C.; Chen, W. K. 1995, "Synthesis of Pyrido[b]cyclobuten-5-one and 1-Azafulvenallene by Flash Vacuum Pyrolysis of 3-Chloroformyl-2-
methylpyridine" , Tetrahedron Lett. 36, 5065-5068.

5.     Chou, C. H.; Trahanovsky, W. S. 1995, Reaction of Furan-Based ortho-
Quinodimethanes with Triplet Oxygen. Formation of Cyclic Peroxides, J. Org. Chem. 60, 5449-5451. 

6.     Liao, L. F.; Teng, P. W.; Chou, C. H.*; Chou, W. C.; Fang, J. M. 1995, A Study of 2-Propenethials Obtained by Flash Vacuum Pyrolysis of 2-Ethenyl-1,3- dithiolane 1,1-Dioxides, Heterocycles, 41, 1967-1977. (NSC-82-0115-C-110-0006).

7.     Shiea, J. T.; Wang, W. S.; Wang, C. H.; Chen, P. S.; Chou, C. H. 1996, "Analysis of a reactive dimethylene dihydrothiophene in methylene chloride by low temperature atmospheric pressure ionization mass spectrometry" Anal. Chem. 68, 1062-1066.

8.     Lu, Y. H.; Hsu, C. S.; Chou, C. H.*; Chou, T. H. 1996, "Preparation of Poly(2,5-thienyleneethylene) and Poly(2,5furyleneethylene)by Vapor Phase Pyrolysis f (5-Methyl-2thienyl)methyl Benzoate and (5-Methyl-2-furyl)methyl Benzoate", Macromolecules, 29, 5546-5550.

9.     Chen, P. S.; Chou, C. H.* 1996, "Pyrolytic Chemistry of Thenyl Benzoates", Tetrahedron, 52, 13615-13622.

10. Chen, P.S.; Chou, C. H.* 1997, "Study of the Pyrolytic Chemistry of   Isobenzofurylmethyl Benzoates" Tetrahedron, 53, 17115-17126. (NSC86-2113-M110-011).

11. Wang, W. S.; Tseng, P. W.; Chou, C. H.; Shiea, J. T. 1998, "Detection of Reactive 1,2,3-Hexatriene-5-one Monomer by Low Temperature Atmospheric Pressure IonizationMass Spectrometry", Rapid Commun. Mass Spectrom. 12, 931-934.

12. Chen, P. S.; Tai, C. L.; Chou, C. H.* 1998, "Pyrolytic Chemistry of (1-Isonaphthofuryl) methyl Benzoate", Tetrahedron Lett. 39, 7381-7384. (NSC86-2113-M110-011).

13.Chiu, S. J.; Chou, C. H.* 1999, "Facile Synthesis of Reactive Benoazetinone by Flash Vacuum Pyrolysis of Isatonic Anhydirde" Tetrahedron Lett., 40, 9271-9272.

14.Ding, S. W.; Ye, C. H.; Chen, C. L.; Chou, C. H. 2002, “The Validity of High  Temperature Approximation in NMR Spectroscopy and Its Related Problems” Chin. J. Mag. Reson. 19, 107-114.

15. Chou, C. H.*; Chiu, S. J.; Liu, W. M. 2002, “Synthesis of Pyridothietone by Flash Vacuum Pyrolysis of 2-Mercaptonicotinic Acid”, Tetrahedron Lett. 43, 5285-5286. (NSC87-2113-M110-006)

16. Chou, C. H.*; Chu, L. T.; Chiu, S. J.; Lee, C. F.; She, Y. T. 2004, “Synthesis of N,N-Di[-1-arylmethylidene]arylmethanediamines by Flash Vacuum Pyrolysis of Arylmethylazides”, Tetrahedron, 60, 6581-6584.

17. Hsu, Y. T.; Chou, C. H.* 2006, “Synthesis of Phenanthridines by Flash Vacuum Pyrolysis of N-Benzylideneanilines”, J. Chin. Chem. Soc. 53, 1215-1218.

18. Chu, L. T.; Yu, P. C.; Wu, B. J.; Liao, Y. C.; Chou, C. H.* 2007, “Synthesis of Areno[e]indenes by the Flash Vacuum Pyrolysis of 4-Methyoxystyrylarenes”, Heterocycles, 73, 165-173.

19. Chou, C. H.*; Chu, L. T.; Chen, I. Y.; Wu, B. J. 2008, “Pyrolytic Study of Cyclic 2-Azidoketones”, Heterocycles, 75, 577-582.

20. Tseng, P. W.; Yeh, S. W.; Chou, C. H.* 2008, “Syntheses and Pyrolyses of Benzofuran Analogues of {Oxo-o-quinodimethane. A Study on Vinylcarbene-Cyclopropene Rearrangement”, J. Org. Chem. 73, 3481-3485.

21. Chou, C. H.*; Yu, P. C.; Wang, B. C. 2008, “Syntheses of 2-Arylbenzothiazoles from Flash Vacuum Pyrolyses and Photolyses of 2-Methylthio-N-(arenylidene)anilines”, Tetrahedron Lett. 49, 4145-4146.

22.Chou, C. H. ; Hsueh, Y. T.; Wang, B. C.2011, " Synthesis of 2-Arylbenzoxazoles from Flash Vacuum pyrolysis of 2-Methoxy-N-(arenylidene)anilines " , J. Chin. Chem. Soc. 58. 301-305.

23. Tseng, P. W. ; Kung, C. Y.; Chen, H. Y.;Chou, C. H. 2011, " Syntheses and Pyrolyses of Furan Analogues of a-Oxa-o-quinodimethanes. Formation of Methylenecyclobutenone and 1-Buten-3-yne via a Vinylcarbene-Cyclopropene Rearrangement " , J. Org. Chem. 76, 8440-8446